An example of treatment of Cu-Cd slag by a lead-zinc joint enterprise replacement method in the former Soviet Union

Wu Siji former Soviet Union -卡敏诺哥尔Trask electrical lead zinc conglomerate zinc plant is to replace Cu-Cd precipitation process slag a centrifugal reactor, the production process shown in Figure 1.

Figure 1 Tungstensky-Kaminnogorsk electric zinc plant processing copper cadmium slag production process

The centrifugal reaction separator has a cylindrical shape and a hollow shaft at the center. The shaft is equipped with a special structure separation disc, and the rotation speed of the hollow shaft reaches 3000r/min.

The rate of displacement of the precipitate in the centrifugal reactor was more than 300 times the precipitation rate of the general displacement sedimentation tank, and the productivity per liter volume reached 200 L/h. The low-cadmium cotton obtained in the second-stage centrifugal reactor is dissolved with zinc waste electrolyte, heated to 343K, and the final pH of the reaction is 4.5-5.5, and then purified by KMnO 4 to remove the ruthenium , and then sent to the centrifugal reactor for replacement. cadmium.

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